Singleton and A. A.
Thomas, J. Am. Chem. Soc.1995, 117, 9357-8.
(For commentaries see Chemical and Engineering News, September 18,
1995, and Lucero, M. J.; Houk, K. N. Chemtracts–Org. Chem.1996, 9, 72.)
"Synchronous
or Asynchronous? An "Experimental" Transition State from a
Direct Comparison of Experimental and Theoretical Kinetic Isotope
Effects for a Diels-Alder Reaction," B. R. Beno, K. N. Houk, and
D. A. Singleton, J. Am. Chem. Soc.1996, 118,
9984-5.
"The
Experimental Geometry of the Epoxidation Transition State," D.
A. Singleton,S. R. Merrigan, J. Liu,
and K. N. Houk, J. Am. Chem. Soc.1997, 119,
3385-6.
"13C
Kinetic Isotope Effects for the Addition of Lithium Dibutylcuprate to
Cyclohexenone. Reductive Elimination is Rate-Determining," D.
E. Frantz, D. A. Singleton,and J. P.
Snyder, J. Am. Chem. Soc., 1997, 119, 3383-4.
"Experimental
and Theoretical Kinetic Isotope Effects for Asymmetric
Dihydroxylation. Evidence Supporting a Rate-Limiting "(3 + 2)"
Cycloaddition," A. J. DelMonte, J. Haller, K. N. Houk, K. B.
Sharpless, D. A. Singleton, T. Straßner, and A. A. Thomas, J.
Am. Chem. Soc.1997, 119, 9907-9908.
"Deuterium
Kinetic Isotope Effects and the Mechanism of the Bacterial Luciferase
Reaction," W. A. Francisco, H. M. Abu-Soud, A. J. DelMonte, D.
A. Singleton, T. O. Baldwin and F. M. Raushel, Biochemistry1998, 37, 2596.
"Experimental
Proof of the Non-Least Motion Cycloadditions of Dichlorocarbene to
Alkenes: Kinetic Isotope Effects and Quantum Mechanical Transition
States," A. E. Keeting, S. R. Merrigan, D. A. Singleton, and K.
N. Houk, J. Am. Chem. Soc.1999, 121, 3933-38.
"Stereochemical
Labeling at Natural Abundance. Stereochemistry, Isotope Effects, and
Mechanism of the Diels-Alder Reaction of Hexachlorocyclopentadiene
with Ethyl Vinyl Ether," D. A. Singleton,* S. R. Merrigan, and
A. A. Thomas, Tetrahedron Lett.1999, 40,
639-642.
"Separation of
the Primary and Secondary Kinetic Isotope Effects at a Reactive
Center Using Starting Material Reactivities. Application to the
FeCl3-Catalyzed Oxidation of C-H Bonds with tert-Butyl
Hydroperoxide," S. R. Merrigan, V. N. Le Gloahec, J. A. Smith,
D. H. R. Barton, and D. A. Singleton, Tetrahedron Lett.1999,
40, 3847-50.
"Isotope
Effects for Lewis Acid-Catalyzed Diels-Alder Reactions. The
Experimental Transition State," D. A. Singleton, S.
R. Merrigan, B. R. Beno, and K. N. Houk, Tetrahedron Lett.1999, 40, 5817-21.
"13C
and 2H Kinetic Isotope Effects and the
Mechanism of Bromination of 1-Pentene under Synthetic Conditions,"
S. R. Merrigan and D. A. Singleton, Org. Lett.1999, 1,
327-330.
"Evidence for
a Concerted Mechanism in a Palladium Trimethylenemethane
Cycloaddition," D. A. Singleton and B. E. Schulmeier, J. Am.
Chem. Soc.1999, 121, 9313-9317.
"Simultaneous
Determination of Intermolecular and Intramolecular 13C
and 2H Kinetic Isotope Effects at
Natural Abundance,"D. A. Singleton and M. J. Szymanski,
J. Am. Chem. Soc.1999, 121, 9455-9456.
"Reinvestigation
of the Isotope Effects for the Claisen and Aromatic Claisen
Rearrangements. The Nature of the Claisen Transition States"M. P. Meyer, A. J. DelMonte, and D. A. Singleton, J. Am. Chem.
Soc.1999, 121, 10865-10874.
"Isotope
Effects and the Experimental Transition State for a Prototypical
Thermal Ene Reaction,"
D. A. Singleton and C. Hang, Tetrahedron Lett.1999, 40, 8939-8942.
"Isotope
Effects and the Mechanism of Triazolinedione Ene Reactions.
Aziridinium Imides are Innocent Bystanders," D. A. Singleton and
C. Hang, J. Am. Chem. Soc.1999, 121,
11885-11893.
"13C
and 2H Kinetic Isotope Effects and the
Mechanism of Lewis acid-Catalyzed Ene Reactions of Formaldehyde,"
D. A. Singleton and C. Hang, J. Org. Chem.2000, 65,
895-899.
"13C
Kinetic Isotope Effects and the Mechanism of the Uncatalyzed
Decarboxylation of Orotic Acid," D. A. Singleton, S. R.
Merrigan, B. J. Kim, P. Beak, L. M. Phillips, and J. K. Lee, J.
Am. Chem. Soc.2000, 122, 3296-3300.
"Isotope
Effects and the Mechanism of Chlorotrimethylsilane-Mediated Addition
of Cuprates to Enones," D. E. Frantz and D. A. Singleton, J.
Am. Chem. Soc.2000, 122, 3288-3295.
“Isotope Effects
and the Mechanism of Allylic Hydroxylation of Alkenes with Selenium
Dioxide,” D. A. Singleton and C. Hang, J. Org. Chem.2000,
65, 7554-7560.
“Resolution of
Conflicting Mechanistic Observations in Ester Aminolysis. A Warning
on the Qualitative Prediction of Isotope Effects for Reactive
Intermediates,” D. A. Singleton and S. R. Merrigan, J. Am. Chem.
Soc.2000, 122, 11035-6.
“Isotope effects
and the distinction between synchronous, asynchronous, and stepwise
Diels-Alder reactions,” D. A. Singleton, B. E. Schulmeier, C. Hang,
A. A. Thomas, S.-W. Leung, and S. R. Merrigan, Tetrahedron2001, 57, 5149-5160.
“The Minimum
Energy Structure of Hydridotris(pyrazolyl)borato Iridium(V)
Tetrahydride Is Not a C3v Capped Octahedron,” C. E. Webster, D. A.
Singleton, M. J. Szymanski, M. B. Hall, C. Zhao, G. Jia, and Z. Lin,
J. Am. Chem. Soc.2001, 123, 9822-9829.
“Mechanism and
Origin of Stereoselectivity in Lewis Acid-Catalyzed [2 + 2]
Cycloadditions of Ketenes with Aldehydes,” D. A. Singleton, Y.
Wang, H. W. Yang, and D. Romo, Angew. Chem. Internat. Ed.2002, 41, 1572-1575.
"Isotope Effects and the Mechanism of an
Electron-Transfer-Catalyzed Diels-Alder Reaction," Saettel, N.
J.; Wiest, O.; Singleton, D. A.; Meyer, M. P. J. Am. Chem. Soc.2002, 124, 11552-11559.
"Mechanism of
Ene Reactions of Singlet Oxygen. A Two-Step No-Intermediate
Mechanism," D. A. Singleton, C. Hang, M. J. Szymanski, M. P.
Meyer, A. G. Leach, K. T. Kuwata, J. S. Chen, A. Greer,
C. S. Foote, and K. N. Houk, J. Am. Chem. Soc.2003,
125, 1319-1328.
"A New Form of
Kinetic Isotope Effect. Dynamic Effects on Isotopic Selectivity and
Regioselectivity," D. A. Singleton, C. Hang, M. J. Szymanski,
and E. E. Greenwald, J. Am. Chem. Soc.2003, 125,
1176-1177.
"Isotope Effects and the Nature of Selectivity in
Rhodium-Catalyzed Cyclopropanations," D. T. Nowlan III, T. M.
Gregg, H. M. L. Davies, and D. A. Singleton, J. Am. Chem. Soc.2003, 125, 15902-15911.
"Isotope Effects and the Mechanism of Atom Transfer Radical
Polymerization," D. A. Singleton,D. T. Nowlan III,
N. Jahed, and K. Matyjaszewski, Macromolecules2003,
36, 8609-8616.
"Isotope
Effects and the Nature of Stereo- and Regioselectivity in
Hydroaminations of Vinylarenes Catalyzed by Palladium(II)-
diphosphine Complexes." L. K. Vo and D. A. Singleton, Org.
Lett.2004, 6, 2469-2472.
“Isotope Effects and the Mechanism of Fragmentation of Epoxy
Imino-1,3,4-oxadiazolines.” D. A. Singleton and Z. Wang,
Tetrahedron Lett.2005, 46, 819-822.
"Isotope
Effects and the Mechanism of Palladium-Catalyzed Allylic
Alkylations," C. F. Christian and D. A. Singleton, Tetrahedron
Lett.2005, 46, 1631-1634.
"Isotope Effects,
Dynamics, and the Mechanism of Solvolysis of Aryldiazonium Cations in
Water," B. R. Ussing and D. A. Singleton, J. Am. Chem. Soc.2005, 127, 2888-2899.
"The Normal Range for
Secondary Swain-Schaad Exponents Without Tunneling or Kinetic
Complexity," J. Hirschi and D. A. Singleton, J. Am. Chem.
Soc.2005, 127, 3294-3295.
"Isotope
Effects and the Mechanism of Deoxygenation of Epoxides with
Dichlorocarbene," D. A. Singleton and Z. Wang, Tetrahedron
Lett.2005, 46, 2033-2036.
"Isotope
Effects and the Nature of Enantioselectivity in the Shi Epoxidation.
The Importance of Asynchronicity," D. A. Singleton and Z.
Wang, J. Am. Chem. Soc.2005, 127, 6679-6685.
"Mechanism and Origin of
Enantioselectivity in the Rh2(OAc)(DPTI)3-Catalyzed
Cyclopropenation of Alkynes," D. T. Nowlan III and D. A.
Singleton, J. Am. Chem.
Soc.2005, 127, 6190-6191.
"'Concerted' Transition State, Stepwise Mechanism. Dynamics
Effects in C2-C6 Enyne Allene Cyclizations,"
T. Bekele, M. A. Lipton, D. A. Singleton and C. F. Christian, J.
Am. Chem. Soc.2005, 127, 9216-9223.
"Dynamic
Effects on the Periselectivity, Rate, Isotope Effects, and Mechanism
of Cycloadditions of Ketenes with Cyclopentadiene," B.
R. Ussing and D. A. Singleton, J. Am. Chem. Soc.2006, 128, 7594-7607.
"Isotope Effects and the Mechanism of Epoxidation of Cyclohexenone wth tert-Butyl Hydroperoxide," C. F. Christian, T. Takeya, M. J. Szymanski, and D. A. Singleton, J. Org. Chem.2007, ASAP.
